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Mendeleev Communications, 1999, Volume 9, Issue 3, Pages 109–111
DOI: https://doi.org/10.1070/MC1999v009n03ABEH001090
(Mi mendc4549)
 

This article is cited in 8 scientific papers (total in 8 papers)

2,5-Diazabicyclo[2.2.2]octane-3,6-dione-1,4-dicarboxylic acids: synthesis, resolution, absolute configuration and crystal structures of the racemic and (–)-enantiomeric forms

R. G. Kostyanovskya, Yu. I. El'natanova, O. N. Krutiusa, K. A. Lyssenkob, I. I. Chervina, D. A. Lenevc

a N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation
b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
c Higher Chemical College of the Russian Academy of Sciences, D.I. Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation
Full-text PDF (215 kB) Citations (8)
Abstract: Title dilactam diacid 1 has been synthesised and resolved into enantiomers via diastereomeric salts 2 with a chiral amine; the absolute configuration of (1R,4R)-(–)-1 was established by decarboxylation and transformation into the parent dilactam (1R,4R)-(–)-C ; the molecular and crystal structures of (±)-1 and (–)-1 (space groups P21/n and P21, respectively) were determined.
Document Type: Article
Language: English


Citation: R. G. Kostyanovsky, Yu. I. El'natanov, O. N. Krutius, K. A. Lyssenko, I. I. Chervin, D. A. Lenev, “2,5-Diazabicyclo[2.2.2]octane-3,6-dione-1,4-dicarboxylic acids: synthesis, resolution, absolute configuration and crystal structures of the racemic and (–)-enantiomeric forms”, Mendeleev Commun., 9:3 (1999), 109–111
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  • This publication is cited in the following 8 articles:
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