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This article is cited in 9 scientific papers (total in 9 papers)
Synthesis and stereochemical features of 2-oxo-3-cyano-1,2-thiaphosphorinanes
I. L. Odinets, N. M. Vinogradova, O. I. Artyushin, P. V. Petrovskii, K. A. Lyssenko, M. Yu. Antipin, T. A. Mastryukova A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
Abstract:
The intramolecular Pishchimuka rearrangement of 3-halopropyl-substituted thiophosphorylacetonitriles results in the corresponding 2-oxo-3-cyano-1,2-thiaphosphorinanes as a statistical mixture of two diastereomers, which transforms to an individual diastereomer with time; in benzene solution, the latter turns again into an equilibrium mixture of diastereomers.
Citation:
I. L. Odinets, N. M. Vinogradova, O. I. Artyushin, P. V. Petrovskii, K. A. Lyssenko, M. Yu. Antipin, T. A. Mastryukova, “Synthesis and stereochemical features of 2-oxo-3-cyano-1,2-thiaphosphorinanes”, Mendeleev Commun., 9:4 (1999), 158–160
Linking options:
https://www.mathnet.ru/eng/mendc4573 https://www.mathnet.ru/eng/mendc/v9/i4/p158
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