Abstract:
Ethyl 3-alkoxy-2-cyanopropanoates were prepared by the reaction of ethyl 2-cyanoacrylate with the corresponding linear alkanols C6–C12 in acidic medium. Their treatment with water as a weak nucleophile resulted in elimination of the alkanol and the formation of oligocyanoacrylate terminated with the alkoxy group. The oligomers were studied by NMR spectroscopy, IR spectroscopy, MALDI-TOF mass-spectrometry and dynamic light scattering.
Citation:
V. A. Dyatlov, V. G. Kharitonova, D. V. Kupriyanova, E. G. Krivoborodov, I. A. Derevnin, A. I. Kovalev, I. A. Khotina, “Oligomers based on cyanoacrylic acid esters”, Mendeleev Commun., 33:4 (2023), 565–567
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https://www.mathnet.ru/eng/mendc461
https://www.mathnet.ru/eng/mendc/v33/i4/p565
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