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Mendeleev Communications, 2023, Volume 33, Issue 4, Pages 565–567
DOI: https://doi.org/10.1016/j.mencom.2023.06.040
(Mi mendc461)
 

This article is cited in 2 scientific papers (total in 2 papers)

Communications

Oligomers based on cyanoacrylic acid esters

V. A. Dyatlova, V. G. Kharitonovab, D. V. Kupriyanovab, E. G. Krivoborodova, I. A. Derevnina, A. I. Kovalevb, I. A. Khotinab

a D.Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation
b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
Abstract: Ethyl 3-alkoxy-2-cyanopropanoates were prepared by the reaction of ethyl 2-cyanoacrylate with the corresponding linear alkanols C6–C12 in acidic medium. Their treatment with water as a weak nucleophile resulted in elimination of the alkanol and the formation of oligocyanoacrylate terminated with the alkoxy group. The oligomers were studied by NMR spectroscopy, IR spectroscopy, MALDI-TOF mass-spectrometry and dynamic light scattering.
Keywords: ethyl 2-cyanoacrylate, fatty alcohols, oligomers, MALDI-TOF mass-spectrometry, nanocapsules, dynamic light scattering.
Bibliographic databases:
Document Type: Article
Language: English
Supplementary materials:
Supplementary_data_1.pdf (603.8 Kb)


Citation: V. A. Dyatlov, V. G. Kharitonova, D. V. Kupriyanova, E. G. Krivoborodov, I. A. Derevnin, A. I. Kovalev, I. A. Khotina, “Oligomers based on cyanoacrylic acid esters”, Mendeleev Commun., 33:4 (2023), 565–567
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  • https://www.mathnet.ru/eng/mendc/v33/i4/p565
  • This publication is cited in the following 2 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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