|
This article is cited in 3 scientific papers (total in 3 papers)
Synthesis and unusual rearrangement of 2-organyl-4,4,6,6-tetramethyl-5-chloro-6λ5-sila-Δ2-dihydro-1,3,4λ4-oxadiazinium chlorides
B. A. Gostevskii, O. B. Kozyreva, V. A. Pestunovich, Yu. A. Chuvashev, V. A. Lopyrev, M. G. Voronkov
A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russian Federation
Abstract:
The reactions of O-TMS derivatives of 1,1-dimethylhydrazides of trifluoroacetic and benzoic acids with Me2Si(CHCl2)Cl give 2-organyl-4,4,6,6-tetramethyl-5-chloro-6λ5-sila-Δ2-dihydro-1,3,4λ4-oxadiazinium chlorides which in CDCl3 solution exhibit unexpected decomposition with the formation of Me2SiCl2, DMF and the corresponding organylcyanide.
Citation:
B. A. Gostevskii, O. B. Kozyreva, V. A. Pestunovich, Yu. A. Chuvashev, V. A. Lopyrev, M. G. Voronkov, “Synthesis and unusual rearrangement of 2-organyl-4,4,6,6-tetramethyl-5-chloro-6λ5-sila-Δ2-dihydro-1,3,4λ4-oxadiazinium chlorides”, Mendeleev Commun., 8:4 (1998), 157–158
Linking options:
https://www.mathnet.ru/eng/mendc4706 https://www.mathnet.ru/eng/mendc/v8/i4/p157
|
|
Contact us: