L. A. Ponomarenko, S. K. Dedushenko, Yu. M. Kiselev, N. A. Chumaevskii, “A magnetochemical study of sodium ferrate”, Mendeleev Commun., 8:5 (1998), 189

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Mendeleev Communications, 1998, Volume 8, Issue 5, Pages 189–190
DOI: https://doi.org/10.1070/MC1998v008n05ABEH000975 (Mi mendc4721)

This article is cited in 2 scientific papers (total in 2 papers)

A magnetochemical study of sodium ferrate

L. A. Ponomarenko^a, S. K. Dedushenko^b, Yu. M. Kiselev^c, N. A. Chumaevskii^b

^a Department of Physics, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^b N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^c Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

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DOI: https://doi.org/10.1070/MC1998v008n05ABEH000975

Abstract: A magnetochemical study of sodium ferrate samples obtained by heating sodium peroxide and iron(III) oxide at about 480 °C and in a 10:1 molar ratio of sodium to iron has shown that there exists a phase of iron in a higher oxidation state which, in terms of quenched orbital magnetism theory, can be considered as a high-spin oxocomplex of tetravalent iron, which is antiferromagnetic with a Neel temperature of about 14 K.

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Document Type: Article

Language: English

Citation: L. A. Ponomarenko, S. K. Dedushenko, Yu. M. Kiselev, N. A. Chumaevskii, “A magnetochemical study of sodium ferrate”, Mendeleev Commun., 8:5 (1998), 189–190

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