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Reactions of chelated PtII and PtIII imidoimino complexes: N-nitrosation involving transfer of an NO group from inorganic nitrites and nitrates
M. O. Ponina, A. A. Sidorov, S. E. Nefedov, I. L. Eremenko, I. I. Moiseev
N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
Abstract:
A bis-chelated imidoimino PtII complex, [(NPh)(N)C6H4]2Pt 1, was found to undergo N-nitrosation on reacting with AgNO2 or AgNO3 to form a product of formal HNO addition, [(NPh)(NNO)C6H4][(NPh)(NH)C6H4]Pt 3, that was characterised by X-ray analysis; similarly, an amidoimino binuclear PtIII complex was converted into 3 by reacting with NaNO2.
Citation:
M. O. Ponina, A. A. Sidorov, S. E. Nefedov, I. L. Eremenko, I. I. Moiseev, “Reactions of chelated PtII and PtIII imidoimino complexes: N-nitrosation involving transfer of an NO group from inorganic nitrites and nitrates”, Mendeleev Commun., 8:6 (1998), 207–208
Linking options:
https://www.mathnet.ru/eng/mendc4731 https://www.mathnet.ru/eng/mendc/v8/i6/p207
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