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This article is cited in 16 scientific papers (total in 16 papers)
Synthesis of 1H- and 1-vinyl-2-pyridylpyrroles by the Trofimov reaction
O. V. Petrova, A. I. Mikhaleva, L. N. Sobenina, E. Yu. Schmidt, E. I. Kositsyna
A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russian Federation
Abstract:
A one-pot synthesis of 2-(2-pyridyl)-1H-pyrrole and 1-vinyl-2-(2-pyridyl)-, 1-vinyl-2-(3-pyridyl)- and 1-vinyl-2-(4-pyridyl)-pyrroles from oximes of 2-acetyl-, 3-acetyl- and 4-acetylpyridine and acetylene under pressure (16–25 atm) in a KOH/DMSO system has been carried out (105–120 °C, 3 h) to reveal for the first time the applicability of the Trofimov reaction for the preparation of alkaloids of the nicotine series.
Citation:
O. V. Petrova, A. I. Mikhaleva, L. N. Sobenina, E. Yu. Schmidt, E. I. Kositsyna, “Synthesis of 1H- and 1-vinyl-2-pyridylpyrroles by the Trofimov reaction”, Mendeleev Commun., 7:4 (1997), 162–163
Linking options:
https://www.mathnet.ru/eng/mendc4836 https://www.mathnet.ru/eng/mendc/v7/i4/p162
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