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This article is cited in 3 scientific papers (total in 3 papers)
Methyl 2-trifluoromethylaziridine-2-carboxylate: stereodirected N-halogenation from the sterically more hindered side
V. V. Rozhkova, K. N. Makarovb, S. N. Osipovb, I. I. Chervina, A. V. Ignatenkoc, R. G. Kostyanovskya
a N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation
b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
c N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
Abstract:
N-Fluorination and N-chlorination of methyl 2-trifluoromethylaziridine-2-carboxylate occurs predominantly from the more hindered side owing to the fixed orientation of the lone electron pair of the N atom caused by the formation of an intramolecular H-bond.
Citation:
V. V. Rozhkov, K. N. Makarov, S. N. Osipov, I. I. Chervin, A. V. Ignatenko, R. G. Kostyanovsky, “Methyl 2-trifluoromethylaziridine-2-carboxylate: stereodirected N-halogenation from the sterically more hindered side”, Mendeleev Commun., 7:6 (1997), 229–230
Linking options:
https://www.mathnet.ru/eng/mendc4869 https://www.mathnet.ru/eng/mendc/v7/i6/p229
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