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Mendeleev Communications, 2023, Volume 33, Issue 5, Pages 717–720
DOI: https://doi.org/10.1016/j.mencom.2023.09.040
(Mi mendc505)
 

This article is cited in 3 scientific papers (total in 3 papers)

Communications

Green coupling of 3,5-diamino-1H-1,2,4-triazole into the azo compound

M. Xiea, J. Gonga, J. Zhoua, J. Wanga, Yu. Caoa, T. Zhouab, Ya. Daiac

a Department of Chemistry, Southwest University of Science and Technology, Mianyang, P.R. China
b Xi'an Modern Chemistry Research Institute, Xi'an, P.R. China
c School of Materials Science and Engineering, Southwest University of Science and Technology, Mianyang, P.R. China
Abstract: The nitrogen–nitrogen double bond between two molecules of 3,5-diamino-1H-1,2,4-triazole is successfully constructed using a one-step electrochemical coupling method. The oxidation occurs selectively when the electrochemical parameters are properly adjusted to provide a yield of 45.77%. Subsequently, the oxidative coupling of this substrate with electrochemically generated hydroxy nickel oxide or sodium hypochlorite is verified.
Keywords: electrochemical synthesis, conjugation reaction, active site, clean and efficient, triazoles, azo compounds, voltage control.
Bibliographic databases:
Document Type: Article
Language: English
Supplementary materials:
Supplementary_data_1.pdf (747.3 Kb)


Citation: M. Xie, J. Gong, J. Zhou, J. Wang, Yu. Cao, T. Zhou, Ya. Dai, “Green coupling of 3,5-diamino-1H-1,2,4-triazole into the azo compound”, Mendeleev Commun., 33:5 (2023), 717–720
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  • This publication is cited in the following 3 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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