|
A 31P CIDNP Study of the Reactions of Dithiophosphate Metal Complexes at Various Magnetic Fields
R. M. Gainullina, A. V. Il'yasova, K. M. Salikhovb a A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation
b E.K. Zavoiskii Kazan' Physicotechnical Institute, Kazan Scientific Centre of the Russian Academy of Sciences, Russian Federation
Abstract:
The reactions of dithiophosphate metal complexes of zinc(II), nickel(II), copper(VI) and molybdenum(vi) with cumene and tert-butyl hydroperoxides have been investigated by 31P CIDNP and the reaction rate constants determined; information about the spin dynamics of the radical pair has been obtained.
Citation:
R. M. Gainullin, A. V. Il'yasov, K. M. Salikhov, “A 31P CIDNP Study of the Reactions of Dithiophosphate Metal Complexes at Various Magnetic Fields”, Mendeleev Commun., 5:3 (1995), 113–114
Linking options:
https://www.mathnet.ru/eng/mendc5057 https://www.mathnet.ru/eng/mendc/v5/i3/p113
|
|