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Mendeleev Communications, 1995, Volume 5, Issue 3, Pages 113–114
DOI: https://doi.org/10.1070/MC1995v005n03ABEH000483
(Mi mendc5057)
 

A 31P CIDNP Study of the Reactions of Dithiophosphate Metal Complexes at Various Magnetic Fields

R. M. Gainullina, A. V. Il'yasova, K. M. Salikhovb

a A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation
b E.K. Zavoiskii Kazan' Physicotechnical Institute, Kazan Scientific Centre of the Russian Academy of Sciences, Russian Federation
Abstract: The reactions of dithiophosphate metal complexes of zinc(II), nickel(II), copper(VI) and molybdenum(vi) with cumene and tert-butyl hydroperoxides have been investigated by 31P CIDNP and the reaction rate constants determined; information about the spin dynamics of the radical pair has been obtained.
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Document Type: Article
Language: English


Citation: R. M. Gainullin, A. V. Il'yasov, K. M. Salikhov, “A 31P CIDNP Study of the Reactions of Dithiophosphate Metal Complexes at Various Magnetic Fields”, Mendeleev Commun., 5:3 (1995), 113–114
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