R. G. Kostyanovsky, A. G. Korepin, P. V. Galkin, Yu. I. El'natanov, G. K. Kadorkina, I. I. Chervin, V. R. Kostyanovsky, “A Superstable Nitrogen Pyramid: Stereodirected N-Halogenation of Methyl 2-Aziridinecarboxylate”, Mendeleev Commun., 5:6 (1995), 216

Mendeleev Communications

RUS ENG

JOURNALS PEOPLE ORGANISATIONS CONFERENCES SEMINARS VIDEO LIBRARY PACKAGE AMSBIB

JavaScript is disabled in your browser. Please switch it on to enable full functionality of the website

	General information
	Latest issue
	Archive

	Search papers
	Search references

	RSS
	Latest issue
	Current issues
	Archive issues
	What is RSS

Mendeleev Commun.:
Year:
Volume:
Issue:
Page:
	Find

Personal entry:
Login:
Password:
	Save password
	Enter
	Forgotten password?
	Register

Mendeleev Communications, 1995, Volume 5, Issue 6, Pages 216–217
DOI: https://doi.org/10.1070/MC1995v005n06ABEH000532 (Mi mendc5106)

This article is cited in 7 scientific papers (total in 7 papers)

A Superstable Nitrogen Pyramid: Stereodirected N-Halogenation of Methyl 2-Aziridinecarboxylate

R. G. Kostyanovsky^a, A. G. Korepin^b, P. V. Galkin^b, Yu. I. El'natanov^a, G. K. Kadorkina^a, I. I. Chervin^a, V. R. Kostyanovsky^a

^a N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation
^b Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation

Full-text PDF (256 kB) Citations (7)

DOI: https://doi.org/10.1070/MC1995v005n06ABEH000532

Abstract: Partial cis-N-halogenation of methyl 2-aziridinecarboxylate (Azy–OMe) takes place only under conditions of intramolecular hydrogen bond breaking under the action of F₂ in the presence of Et₃N, and also under the action of KOCI in the presence of H₂O; for the N-fluoro derivative, a record high nitrogen inversion barrier was found (ΔG^#35 kcal mol^–1).

Bibliographic databases:

Document Type: Article

Language: English

Citation: R. G. Kostyanovsky, A. G. Korepin, P. V. Galkin, Yu. I. El'natanov, G. K. Kadorkina, I. I. Chervin, V. R. Kostyanovsky, “A Superstable Nitrogen Pyramid: Stereodirected N-Halogenation of Methyl 2-Aziridinecarboxylate”, Mendeleev Commun., 5:6 (1995), 216–217

Linking options:

https://www.mathnet.ru/eng/mendc5106

https://www.mathnet.ru/eng/mendc/v5/i6/p216

This publication is cited in the following 7 articles:

Citing articles in Google Scholar: Russian citations, English citations
Related articles in Google Scholar: Russian articles, English articles

Registration to the website

Logotypes