V. N. Kalinin, V. V. Derunov, L. Maat, J. K. Park, H. Schmidhammer, “Synthesis of π-Complexes of Codeine with Iron and Molybdenum”, Mendeleev Commun., 5:6 (1995), 222

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Mendeleev Communications, 1995, Volume 5, Issue 6, Pages 222–223
DOI: https://doi.org/10.1070/MC1995v005n06ABEH000535 (Mi mendc5109)

This article is cited in 3 scientific papers (total in 3 papers)

Synthesis of π-Complexes of Codeine with Iron and Molybdenum

V. N. Kalinin^a, V. V. Derunov^a, L. Maat^b, J. K. Park^c, H. Schmidhammer^d

^a A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
^b Laboratory of Organic Chemistry and Catalysis, Delft University of Technology, Delft, the Netherlands
^c Dong Kook Pharmaceutical Co., Ltd., Seoul, Korea
^d Institute of Pharmacy, University of Innsbruck, Innsbruck, Austria

Full-text PDF (131 kB) Citations (3)

DOI: https://doi.org/10.1070/MC1995v005n06ABEH000535

Abstract: Treatment of 6β-chloro-6-deoxycodeine 1 or 8β-bromo-8-deoxypseudocodeine 2 with Fe(CO)₅ or Fe₂(CO)₉ yields 6-demethoxythebaine 3 and the π-diene iron complex 4; compound 1 or 2 reacts with Mo(CO)₆ to give the π-allylic molybdenum complexes 5 and 6, respectively.

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Document Type: Article

Language: English

Citation: V. N. Kalinin, V. V. Derunov, L. Maat, J. K. Park, H. Schmidhammer, “Synthesis of π-Complexes of Codeine with Iron and Molybdenum”, Mendeleev Commun., 5:6 (1995), 222–223

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