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Mendeleev Communications, 1994, Volume 4, Issue 3, Pages 85–88
DOI: https://doi.org/10.1070/MC1994v004n03ABEH000358
(Mi mendc5162)
 

This article is cited in 10 scientific papers (total in 10 papers)

1,5-Sigmatropic Shifts of Chlorine in the Cyclopentadiene Ring

I. E. Mikhailova, G. A. Dushenkoa, A. V. Kisinb, C. Mueggec, A. Zschunked, V. I. Minkina

a Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russian Federation
b State Scientific Research Institute of Chemistry and Technology of Organoelement Compounds, Moscow, Russian Federation
c Department of Chemistry, Humboldt University, Berlin, Germany
d Federal Institute for Materials Research and Testing, Berlin, Germany
Abstract: Intramolecular rearrangement due to successive 1,5-sigmatropic shifts of chlorine over a five-membered ring were found to occur in 5-chloro-1-alky1-2,3,4,5-tetramethoxycarbonylcyclopentadienes with energy barriers to chlorine migration falling in the range 26.0–27.3 kcal mol–1.
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Document Type: Article
Language: English


Citation: I. E. Mikhailov, G. A. Dushenko, A. V. Kisin, C. Muegge, A. Zschunke, V. I. Minkin, “1,5-Sigmatropic Shifts of Chlorine in the Cyclopentadiene Ring”, Mendeleev Commun., 4:3 (1994), 85–88
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  • This publication is cited in the following 10 articles:
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