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This article is cited in 10 scientific papers (total in 10 papers)
1,5-Sigmatropic Shifts of Chlorine in the Cyclopentadiene Ring
I. E. Mikhailova, G. A. Dushenkoa, A. V. Kisinb, C. Mueggec, A. Zschunked, V. I. Minkina a Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russian Federation
b State Scientific Research Institute of Chemistry and Technology of Organoelement Compounds, Moscow, Russian Federation
c Department of Chemistry, Humboldt University, Berlin, Germany
d Federal Institute for Materials Research and Testing, Berlin, Germany
Abstract:
Intramolecular rearrangement due to successive 1,5-sigmatropic shifts of chlorine over a five-membered ring were found to occur in 5-chloro-1-alky1-2,3,4,5-tetramethoxycarbonylcyclopentadienes with energy barriers to chlorine migration falling in the range 26.0–27.3 kcal mol–1.
Citation:
I. E. Mikhailov, G. A. Dushenko, A. V. Kisin, C. Muegge, A. Zschunke, V. I. Minkin, “1,5-Sigmatropic Shifts of Chlorine in the Cyclopentadiene Ring”, Mendeleev Commun., 4:3 (1994), 85–88
Linking options:
https://www.mathnet.ru/eng/mendc5162 https://www.mathnet.ru/eng/mendc/v4/i3/p85
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