L. P. Olekhnovich, Z. N. Budarina, A. V. Lesin, S. V. Kurbatov, G. S. Borodkin, V. I. Minkin, “Intramolecular Inversion of Configuration at Tetrahedral Carbon Centres in Dipolar Spiro-σ-Complexes of Amino-, Diamino- and Aminothiotropones: a Dynamic NMR Spectral Study”, Mendeleev Commun., 4:5 (1994), 162

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Mendeleev Communications, 1994, Volume 4, Issue 5, Pages 162–164
DOI: https://doi.org/10.1070/MC1994v004n05ABEH000394 (Mi mendc5198)

This article is cited in 16 scientific papers (total in 16 papers)

Intramolecular Inversion of Configuration at Tetrahedral Carbon Centres in Dipolar Spiro-σ-Complexes of Amino-, Diamino- and Aminothiotropones: a Dynamic NMR Spectral Study

L. P. Olekhnovich, Z. N. Budarina, A. V. Lesin, S. V. Kurbatov, G. S. Borodkin, V. I. Minkin

Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russian Federation

Full-text PDF (289 kB) Citations (16)

DOI: https://doi.org/10.1070/MC1994v004n05ABEH000394

Abstract: Inversion of configuration at the tetrahedral carbon centres of dipolar spiro-σ-complexes formed by coupling 2-(N-benzylamino)tropone, 2-(N-benzylamino)thiotropone or N,N’-dibenzyl-2-aminotroponimine with electrophilic aromatic and heterocyclic compounds has been found to occur intramolecularly with energy barriers accessible to measurement by means of dynamic ¹H NMR spectral techniques.

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Document Type: Article

Language: English

Citation: L. P. Olekhnovich, Z. N. Budarina, A. V. Lesin, S. V. Kurbatov, G. S. Borodkin, V. I. Minkin, “Intramolecular Inversion of Configuration at Tetrahedral Carbon Centres in Dipolar Spiro-σ-Complexes of Amino-, Diamino- and Aminothiotropones: a Dynamic NMR Spectral Study”, Mendeleev Commun., 4:5 (1994), 162–164

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This publication is cited in the following 16 articles:

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