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This article is cited in 16 scientific papers (total in 16 papers)
Carbonylation of Methylcyclopentane and Cyclohexane Initiated by the Aprotic Organic Superacid CBr4·2AIBr3
S. Z. Bernadyuk, I. S. Akhrem, M. E. Vol'pin
A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
Abstract:
The aprotic organic superacid CBr4·2AIBr3 initiates carbonylation of methylcyclopentane 1 and cyclohexane 2 with CO at atmospheric pressure with formation (after EtOH treatment) of various products in high yields depending on the conditions. The products are esters of 1-methylcyclopentanecarbonic (1a; at −45 °C) and cyclohexanecarbonic (2a; at 0°C) acids and 2-methylcyclohexanone (3; at − 23 °C); the reaction mechanism is discussed.
Citation:
S. Z. Bernadyuk, I. S. Akhrem, M. E. Vol'pin, “Carbonylation of Methylcyclopentane and Cyclohexane Initiated by the Aprotic Organic Superacid CBr4·2AIBr3”, Mendeleev Commun., 4:5 (1994), 183–185
Linking options:
https://www.mathnet.ru/eng/mendc5210 https://www.mathnet.ru/eng/mendc/v4/i5/p183
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