O. E. Nasakin, P. M. Lukin, E. V. Vershinin, S. V. Lindeman, Yu. T. Struchkov, “Two Alternative Pathways for the Interaction of Hexacyanocyclopropane with Nucleophiles”, Mendeleev Commun., 4:5 (1994), 185

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Mendeleev Communications, 1994, Volume 4, Issue 5, Pages 185–186
DOI: https://doi.org/10.1070/MC1994v004n05ABEH000407 (Mi mendc5211)

This article is cited in 6 scientific papers (total in 6 papers)

Two Alternative Pathways for the Interaction of Hexacyanocyclopropane with Nucleophiles

O. E. Nasakin^a, P. M. Lukin^a, E. V. Vershinin^a, S. V. Lindeman^b, Yu. T. Struchkov^b

^a Department of Chemistry, I.N. Ulyanov Chuvash State University, Cheboksary, Russian Federation
^b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Full-text PDF (204 kB) Citations (6)

DOI: https://doi.org/10.1070/MC1994v004n05ABEH000407

Abstract: Methanol molecules add to the cyano groups of hexacyanocyclopropane 1 in the presence of sodium methylate to give 1,4-adduct 2. The interaction of 1 with N-methylpyridinium iodide leads to opening of the cyclopropane ring and to the formation of propenide 3 and iodine cyanide 4; the structure of 2 was established by an X-ray crystallographic study.

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Document Type: Article

Language: English

Citation: O. E. Nasakin, P. M. Lukin, E. V. Vershinin, S. V. Lindeman, Yu. T. Struchkov, “Two Alternative Pathways for the Interaction of Hexacyanocyclopropane with Nucleophiles”, Mendeleev Commun., 4:5 (1994), 185–186

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This publication is cited in the following 6 articles:

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