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This article is cited in 7 scientific papers (total in 7 papers)
Chlorovinylidenecarbene: Generation from 3,3-Dichloropropyne by Base Solvolysis (under Phase-transfer Catalysis Conditions) and Reaction with Alkenes
K. N. Shavrin, I. B. Shvedova, O. M. Nefedov
N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
Abstract:
The chlorovinylidenecarbene 6 has been generated from 3,3-dichloropropyne 1a via γ-elimination of hydrogen chloride on treatment with powdered KOH under phase-transfer catalysis conditions and has been trapped by alkenes, to form chlorovinylidenecyclopropanes 7 in 20–45% yields.
Citation:
K. N. Shavrin, I. B. Shvedova, O. M. Nefedov, “Chlorovinylidenecarbene: Generation from 3,3-Dichloropropyne by Base Solvolysis (under Phase-transfer Catalysis Conditions) and Reaction with Alkenes”, Mendeleev Commun., 3:2 (1993), 50–51
Linking options:
https://www.mathnet.ru/eng/mendc5260 https://www.mathnet.ru/eng/mendc/v3/i2/p50
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