R. R. Rakhimov, A. I. Semikopny, Ya. S. Lebedev, “Unexpected Influence of Viscosity on Intramolecular Spin Exchange in Nitroxide Biradicals”, Mendeleev Commun., 2:1 (1992), 2

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Mendeleev Communications, 1992, Volume 2, Issue 1, Pages 2–4
DOI: https://doi.org/10.1070/MC1992v002n01ABEH000093 (Mi mendc5364)

This article is cited in 1 scientific paper (total in 1 paper)

Unexpected Influence of Viscosity on Intramolecular Spin Exchange in Nitroxide Biradicals

R. R. Rakhimov^a, A. I. Semikopny^b, Ya. S. Lebedev^c

^a V.I. Nikitin Institute of Chemistry, Academy of Sciences of the Tajikistan, Dushanbe, Tajikistan
^b Institute of Chemistry, Tadzhik Academy of Sciences
^c N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation

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DOI: https://doi.org/10.1070/MC1992v002n01ABEH000093

Abstract: The spin exchange dynamics and the rotational mobility of rigid-frame nitroxide biradicals have been studied by EPR; despite the intramolecular character of the exchange, its rate correlates with molecular mobility, being damped in viscous media, thus proving that even the simplest intramolecular reactions are controlled by molecular dynamics.

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Document Type: Article

Language: English

Citation: R. R. Rakhimov, A. I. Semikopny, Ya. S. Lebedev, “Unexpected Influence of Viscosity on Intramolecular Spin Exchange in Nitroxide Biradicals”, Mendeleev Commun., 2:1 (1992), 2–4

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