V. N. Khabashesku, V. Balaji, S. E. Boganov, S. A. Bashkirova, P. M. Matveichev, E. A. Chernyshev, O. M. Nefedov, J. Michl, “Matrix Isolation and Photochemical Interconversion of Siiacyciopentadienes”, Mendeleev Commun., 2:1 (1992), 38

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Mendeleev Communications, 1992, Volume 2, Issue 1, Pages 38–40
DOI: https://doi.org/10.1070/MC1992v002n01ABEH000118 (Mi mendc5389)

This article is cited in 14 scientific papers (total in 14 papers)

Matrix Isolation and Photochemical Interconversion of Siiacyciopentadienes

V. N. Khabashesku^a, V. Balaji^a, S. E. Boganov^b, S. A. Bashkirova^c, P. M. Matveichev^c, E. A. Chernyshev^c, O. M. Nefedov^b, J. Michl^a

^a Department of Chemistry and Biochemistry, University of Colorado at Boulder, Boulder, USA
^b N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^c State Scientific Research Institute of Chemistry and Technology of Organoelement Compounds, Moscow, Russian Federation

Full-text PDF (564 kB) Citations (14)

DOI: https://doi.org/10.1070/MC1992v002n01ABEH000118

Abstract: 1-Silacyclopenta-2,4-diene 1 has been generated by vacuum pyrolysis of 5-silaspiro[4.4]nona-2,7-diene 5 and by photolysis of matrix-isolated 1,1-diazido-1-silacyclopent-3-ene 6, and characterized by matrix-isolation IR and UV spectroscopy; reversible interconversion of 1 with 1-silacyclopenta-1,3-diene 2, 1-silacyclopenta-1,4-diene 3 and 1-silacyclopent-3-ene-1,1-diyl 4 has been observed upon irradiation at various wavelengths; the red-shifted UV absorption of 2 and 3, together with their low Si=C stretching frequencies, provide evidence for Si=C—C=C π conjugation.

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Document Type: Article

Language: English

Citation: V. N. Khabashesku, V. Balaji, S. E. Boganov, S. A. Bashkirova, P. M. Matveichev, E. A. Chernyshev, O. M. Nefedov, J. Michl, “Matrix Isolation and Photochemical Interconversion of Siiacyciopentadienes”, Mendeleev Commun., 2:1 (1992), 38–40

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This publication is cited in the following 14 articles:

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