A. R. Kudinov, A. A. Filchikov, M. I. Rybinskaya, “Deprotonation and Subsequent Functionalization of Methyl Groups in Cationic Ruthenium Triple-decker Complexes”, Mendeleev Commun., 2:2 (1992), 64

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Mendeleev Communications, 1992, Volume 2, Issue 2, Pages 64–65
DOI: https://doi.org/10.1070/MC1992v002n02ABEH000136 (Mi mendc5407)

This article is cited in 3 scientific papers (total in 3 papers)

Deprotonation and Subsequent Functionalization of Methyl Groups in Cationic Ruthenium Triple-decker Complexes

A. R. Kudinov, A. A. Filchikov, M. I. Rybinskaya

A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Full-text PDF (245 kB) Citations (3)

DOI: https://doi.org/10.1070/MC1992v002n02ABEH000136

Abstract: The cationic complex [(η-C₅Me₅)Ru(μ,η-C₅Me₅)Ru(η-C₅Me₅)]⁺ undergoes deprotonation of the terminal ring methyl groups on treatment with BuⁿLi-Bu’OK at – 78°C in tetrahydrofuran; subsequent treatment with EX reagents gives rise to functionalized complexes [(η-C₅Me₅)Ru(μ,η-C₅Me₅)Ru(η-C₅Me₄CH₂E)]⁺ (E = Me, Me₃Si, EtS).

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Document Type: Article

Language: English

Citation: A. R. Kudinov, A. A. Filchikov, M. I. Rybinskaya, “Deprotonation and Subsequent Functionalization of Methyl Groups in Cationic Ruthenium Triple-decker Complexes”, Mendeleev Commun., 2:2 (1992), 64–65

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https://www.mathnet.ru/eng/mendc/v2/i2/p64

This publication is cited in the following 3 articles:

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