O. M. Nefedov, M. A. Korolev, L. Zanathy, B. Solouki, H. Bock, “The Selective Thermal Fragmentation of 2,2’-Dipropynyl Sulfide to Propynethial and Allene”, Mendeleev Commun., 2:2 (1992), 67

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Mendeleev Communications, 1992, Volume 2, Issue 2, Pages 67–69
DOI: https://doi.org/10.1070/MC1992v002n02ABEH000138 (Mi mendc5409)

This article is cited in 9 scientific papers (total in 9 papers)

The Selective Thermal Fragmentation of 2,2’-Dipropynyl Sulfide to Propynethial and Allene

O. M. Nefedov^a, M. A. Korolev^a, L. Zanathy^b, B. Solouki^c, H. Bock^c

^a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b Institute of General and Inorganic Chemistry, Eotvos University, Budapest, Hungary
^c Institute of Inorganic Chemistry, Johann Wolfgang Goethe-University, Frankfurt, Germany

Full-text PDF (2379 kB) Citations (9)

DOI: https://doi.org/10.1070/MC1992v002n02ABEH000138

Abstract: The thermolysis of 2,2’-dipropynyl sulfide in a flow system under almost unimolecular conditions, which above 830 K selectively yields propynethial and allene, is optimized by photoelectron spectroscopic real-time gas analysis and, according to semiempirical energy hypersurface calculations, possibly proceeds via an intramolecular hydrogen transfer.

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Document Type: Article

Language: English

Citation: O. M. Nefedov, M. A. Korolev, L. Zanathy, B. Solouki, H. Bock, “The Selective Thermal Fragmentation of 2,2’-Dipropynyl Sulfide to Propynethial and Allene”, Mendeleev Commun., 2:2 (1992), 67–69

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This publication is cited in the following 9 articles:

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