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Mendeleev Communications, 2023, Volume 33, Issue 6, Pages 836–838
DOI: https://doi.org/10.1016/j.mencom.2023.10.032
(Mi mendc541)
 

This article is cited in 11 scientific papers (total in 11 papers)

Communications

An egg-shell PdAg/α-Al2O3 single-atom alloy catalyst for selective acetylene hydrogenation

P. V. Markov, I. S. Mashkovsky, G. N. Baeva, D. P. Melnikov, A. Yu. Stakheev

N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
Abstract: The PdAg/α-Al2O3 catalyst with an egg-shell distribution of single-atom alloy (SAA) Pd1Ag nanoparticles was obtained using the complex PdAg2(OAc)4(HOAc)4 as a precursor and characterized by FESEM-EDS, XPS, and DRIFTS CO analysis. The egg-shell Pd1Ag SAA catalyst demonstrated superior selectivity in the hydrogenation of acetylene in acetylene–ethylene feed.
Keywords: acetylene hydrogenation, egg-shell catalyst, single-atom alloy catalyst, PdAg alloy, heterobimetallic complex, catalyst characterization.
Bibliographic databases:
Document Type: Article
Language: English
Supplementary materials:
Supplementary_data_1.pdf (323.7 Kb)


Citation: P. V. Markov, I. S. Mashkovsky, G. N. Baeva, D. P. Melnikov, A. Yu. Stakheev, “An egg-shell PdAg/α-Al2O3 single-atom alloy catalyst for selective acetylene hydrogenation”, Mendeleev Commun., 33:6 (2023), 836–838
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  • This publication is cited in the following 11 articles:
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