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Mendeleev Communications, 1992, Volume 2, Issue 4, Pages 137–139
DOI: https://doi.org/10.1070/MC1992v002n04ABEH000172
(Mi mendc5443)
 

This article is cited in 6 scientific papers (total in 6 papers)

Base Acceleration of Alkane Oxidation by an Iron-porphyrin−Hypochlorite System. Activity, Selectivity and Kinetic Isotope Effect

A. B. Sorokina, A. M. Khenkina, A. E. Shilovb

a Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
b N.M. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, Moscow, Russian Federation
Abstract: Addition of alkali strongly accelerates the oxidation of cyciohexane by an iron tetramesitylporphyrin−NaOCl system, the selectivity of the reaction and the H−D kinetic isotope effect also being affected; possible mechanisms of OH action are discussed
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Document Type: Article
Language: English


Citation: A. B. Sorokin, A. M. Khenkin, A. E. Shilov, “Base Acceleration of Alkane Oxidation by an Iron-porphyrin−Hypochlorite System. Activity, Selectivity and Kinetic Isotope Effect”, Mendeleev Commun., 2:4 (1992), 137–139
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  • https://www.mathnet.ru/eng/mendc/v2/i4/p137
  • This publication is cited in the following 6 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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