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This article is cited in 6 scientific papers (total in 6 papers)
Base Acceleration of Alkane Oxidation by an Iron-porphyrin−Hypochlorite System. Activity, Selectivity and Kinetic Isotope Effect
A. B. Sorokina, A. M. Khenkina, A. E. Shilovb a Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
b N.M. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, Moscow, Russian Federation
Abstract:
Addition of alkali strongly accelerates the oxidation of cyciohexane by an iron tetramesitylporphyrin−NaOCl system, the selectivity of the reaction and the H−D kinetic isotope effect also being affected; possible mechanisms of OH− action are discussed
Citation:
A. B. Sorokin, A. M. Khenkin, A. E. Shilov, “Base Acceleration of Alkane Oxidation by an Iron-porphyrin−Hypochlorite System. Activity, Selectivity and Kinetic Isotope Effect”, Mendeleev Commun., 2:4 (1992), 137–139
Linking options:
https://www.mathnet.ru/eng/mendc5443 https://www.mathnet.ru/eng/mendc/v2/i4/p137
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