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This article is cited in 2 scientific papers (total in 2 papers)
Is there Ring–Chain Tautomerism in γ-Nitrosoalkanols?
V. F. Rudchenko, I. I. Chervin, R. G. Kostyanovsky
N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation
Abstract:
γ-Nitrosoalkanols 2, 6 and 8, obtained upon acid hydrolysis of 2-methoxyisoxazolidines 1 and 7 and of dimethoxyamine 5, respectively, do not display ring–chain tautomerism, i.e. formation of the corresponding 2-hydroxyisoxazolidines (‘heminitrosals’); nitrosoalkanol 2 smoothly rearranges to oxime 4, whilst compound 8 in MeOH gives diol 9, probably via aerial oxidation to the corresponding nitrite followed by denitrosation.
Citation:
V. F. Rudchenko, I. I. Chervin, R. G. Kostyanovsky, “Is there Ring–Chain Tautomerism in γ-Nitrosoalkanols?”, Mendeleev Commun., 1:1 (1991), 9–10
Linking options:
https://www.mathnet.ru/eng/mendc5467 https://www.mathnet.ru/eng/mendc/v1/i1/p9
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