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This article is cited in 12 scientific papers (total in 12 papers)
Radio Induced 12C/13C Magnetic Isotope Effect
V. F. Tarasova, E. G. Bagryanskayab, Yu. A. Grishinb, R. Z. Sagdeevc, A. L. Buchachenkoa
a N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation
b V.V. Voevodsky Institute of Chemical Kinetics and Combustion, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
c International Tomography Center, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
Abstract:
The separation of carbon isotopes 12C and 13C induced by magnetic electron–nuclear interaction in radical pairs is increased by selective microwave pumping at the frequency of EPR transitions in 13C-containing radicals; the pumping accelerates the triplet–singlet conversion of 13C radical pairs and therefore increases the nuclear spin selectivity of chemical reactions; this new effect has been called the radio induced magnetic isotope effect (RIMIE).
Citation:
V. F. Tarasov, E. G. Bagryanskaya, Yu. A. Grishin, R. Z. Sagdeev, A. L. Buchachenko, “Radio Induced 12C/13C Magnetic Isotope Effect”, Mendeleev Commun., 1:3 (1991), 85–86
Linking options:
https://www.mathnet.ru/eng/mendc5512 https://www.mathnet.ru/eng/mendc/v1/i3/p85
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