N. Yu. Kozitsyna, A. M. Ellern, M. Yu. Antipin, Yu. T. Struchkov, I. I. Moiseev, “Unexpected Oxidation of a Coordinated Phosphine Ligand. Synthesis and Molecular Structure of [Pd( μ-O2PPh2)(C6H5)(PPh3)]2”, Mendeleev Commun., 1:3 (1991), 92

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Mendeleev Communications, 1991, Volume 1, Issue 3, Pages 92–94
DOI: https://doi.org/10.1070/MC1991v001n03ABEH000056 (Mi mendc5517)

This article is cited in 14 scientific papers (total in 14 papers)

Unexpected Oxidation of a Coordinated Phosphine Ligand. Synthesis and Molecular Structure of [Pd( μ-O₂PPh₂)(C₆H₅)(PPh₃)]₂

N. Yu. Kozitsyna^a, A. M. Ellern^a, M. Yu. Antipin^b, Yu. T. Struchkov^b, I. I. Moiseev^a

^a N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Full-text PDF (534 kB) Citations (14)

DOI: https://doi.org/10.1070/MC1991v001n03ABEH000056

Abstract: The reaction of [Pd(OAc)₂(PPh₃)]₂ with HCO₂H includes the transfer of an O atom from the carboxylic ligand to the P atom and cleavage of the P—Ph bond accompanied by transfer of the Ph group from PPh₃ ligand to the palladium atom; the structure of the complex formed, [Pd(μ-O₂PPh₂)(C₆H₅)(PPh₃)]₂, has been resolved by X-ray analysis.

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Document Type: Article

Language: English

Citation: N. Yu. Kozitsyna, A. M. Ellern, M. Yu. Antipin, Yu. T. Struchkov, I. I. Moiseev, “Unexpected Oxidation of a Coordinated Phosphine Ligand. Synthesis and Molecular Structure of [Pd( μ-O₂PPh₂)(C₆H₅)(PPh₃)]₂”, Mendeleev Commun., 1:3 (1991), 92–94

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This publication is cited in the following 14 articles:

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