|
This article is cited in 5 scientific papers (total in 5 papers)
Use of 20,20-Dimethylacetal Protection in Microbial Hydroxylation and Dehydrogenation of Steroids
A. M. Turutaa, A. V. Kamernitskiia, N. E. Voishvilloa, N. V. Jlantiashvilia, A. P. Krymovb, N. V. Domrachevb a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
b All-Russia Scientific Centre of Biologically Active Compounds, Moscow region, Russian Federation
Abstract:
The 20,20-dimethylacetal group proposed for protection of the 20-oxo group in 21-hydroxylation of steroids by hypervalent iodine compounds has been successfully used to hamper side reactions in microbial 9α- and 11β-hydroxylation and 4-dehydrogenation of 21-hydroxy-16α,17α-epoxypregnanes by Rhodococcus sp., Curvularia lunata and Corynebacterium mediolanum cultures.
Citation:
A. M. Turuta, A. V. Kamernitskii, N. E. Voishvillo, N. V. Jlantiashvili, A. P. Krymov, N. V. Domrachev, “Use of 20,20-Dimethylacetal Protection in Microbial Hydroxylation and Dehydrogenation of Steroids”, Mendeleev Commun., 1:3 (1991), 113–114
Linking options:
https://www.mathnet.ru/eng/mendc5530 https://www.mathnet.ru/eng/mendc/v1/i3/p113
|
|