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This article is cited in 15 scientific papers (total in 15 papers)
1H CIDNP Study of the Addition Reaction of Me2E (E = Si,Ge) to a Carbon≡Carbon Triple Bond
M. P. Egorova, M. B. Ezhovaa, S. P. Kolesnikova, O. M. Nefedova, M. B. Tarabanb, A. I. Kruppab, T. V. Leshinab a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
b V.V. Voevodsky Institute of Chemical Kinetics and Combustion, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
Abstract:
Addition of Me2E (E = Si.Ge) to the triple bond of 3,3,6,6-tetramethyl-1-thiacyclohept-4-yne proceeds in a nonconcerted way via a 1,3-biradical intermediate; the first experimental evidence of the participation of an excited triplet Me2E species in a chemical reaction has been obtained.
Citation:
M. P. Egorov, M. B. Ezhova, S. P. Kolesnikov, O. M. Nefedov, M. B. Taraban, A. I. Kruppa, T. V. Leshina, “1H CIDNP Study of the Addition Reaction of Me2E (E = Si,Ge) to a Carbon≡Carbon Triple Bond”, Mendeleev Commun., 1:4 (1991), 143–145
Linking options:
https://www.mathnet.ru/eng/mendc5549 https://www.mathnet.ru/eng/mendc/v1/i4/p143
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