S. V. Hirmer, F. S. Tschernuth, F. Hanusch, R. Baierl, M. Muhr, Sh. Inoue, “Modification of bidentate bis(N-heterocyclic imine) ligands for low-valent main group complexes”, Mendeleev Commun., 32:1 (2022), 16

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Mendeleev Communications, 2022, Volume 32, Issue 1, Pages 16–18
DOI: https://doi.org/10.1016/j.mencom.2022.01.004 (Mi mendc556)

This article is cited in 8 scientific papers (total in 8 papers)

Communications

Modification of bidentate bis(N-heterocyclic imine) ligands for low-valent main group complexes

S. V. Hirmer^a, F. S. Tschernuth^a, F. Hanusch^a, R. Baierl^a, M. Muhr^b, Sh. Inoue^a

^a Institute of Silicon Chemistry and Catalysis Research Center, Department of Chemistry, Technical University of Munich, Garching bei München, Germany
^b Department of Chemistry, Technical University of Munich, Garching bei München, Germany

Full-text PDF (294 kB) Citations (8) Supplementary materials

DOI: https://doi.org/10.1016/j.mencom.2022.01.004

Graphic abstract: Modification of bidentate bis(N-heterocyclic imine) ligands for low-valent main group complexes

Abstract: The synthesis of modified neutral bis-NHI (NHI is N-heterocyclic imine) ligands and their application for the stabilization of tetryliumylidenes are reported. The ligands’ scaffolding consists of either saturated or methylated imidazoline backbones, and the bridge alternated from flexible ethylene to more rigid o-phenylene. Transmetalation reactivity of the cationic Sn^II compounds was tested towards LiAlH₄ and IDipp→SiCl₂ [IDipp is 1,3-bis(2,6-diisopropyl- phenyl)imidazol-2-ylidene] affording the respective aluminium and silicon complexes.

Keywords: tin, germanium, silicon, N-heterocyclic imines, tetryliumylidenes, transmetalation.

Bibliographic databases:

Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(1.4 Mb)

Citation: S. V. Hirmer, F. S. Tschernuth, F. Hanusch, R. Baierl, M. Muhr, Sh. Inoue, “Modification of bidentate bis(N-heterocyclic imine) ligands for low-valent main group complexes”, Mendeleev Commun., 32:1 (2022), 16–18

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https://www.mathnet.ru/eng/mendc/v32/i1/p16

This publication is cited in the following 8 articles:

Citing articles in Google Scholar: Russian citations, English citations
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