M. A. Leal, A. L. Rheingold, Ch. S. Weinert, “A facile route to germanium(IV) binaphthoxide complexes: crystal structure of a chiral resolved germanium(IV) binaphthoxide”, Mendeleev Commun., 32:1 (2022), 19

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Mendeleev Communications, 2022, Volume 32, Issue 1, Pages 19–21
DOI: https://doi.org/10.1016/j.mencom.2022.01.005 (Mi mendc557)

Communications

A facile route to germanium(IV) binaphthoxide complexes: crystal structure of a chiral resolved germanium(IV) binaphthoxide

M. A. Leal^a, A. L. Rheingold^b, Ch. S. Weinert^a

^a Department of Chemistry, Oklahoma State University, Stillwater, Oklahoma, USA
^b Department of Chemistry and Biochemistry, University of California, San Diego, California, USA

Full-text PDF (275 kB) Supplementary materials

DOI: https://doi.org/10.1016/j.mencom.2022.01.005

Graphic abstract: A facile route to germanium(IV) binaphthoxide complexes: crystal structure of a chiral resolved germanium(IV) binaphthoxide

Abstract: A method for the facile synthesis of chiral germanium(IV) binaphthoxide complexes from the corresponding binaphthols and an organogermanium trichloride has been developed, which allows these unusual types of compounds to be synthesized in high yields. The crystal structure of one such complex, (S)-[Ge{O2C20H10(SiMe3)2-3,3'}{Cl}{Ph}], has been determined.

Keywords: germanium, organogermanium compounds, phenylgermanium trichloride, chiral binaphthoxides, aryl oxides, crystal structure, metathesis reactions.

Bibliographic databases:

Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(605.4 Kb)

Citation: M. A. Leal, A. L. Rheingold, Ch. S. Weinert, “A facile route to germanium(IV) binaphthoxide complexes: crystal structure of a chiral resolved germanium(IV) binaphthoxide”, Mendeleev Commun., 32:1 (2022), 19–21

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https://www.mathnet.ru/eng/mendc/v32/i1/p19

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