Ya. Egawa, Ch. Kobuna, N. Takeda, M. Unno, “Synthesis of Janus cube containing Si–H moieties”, Mendeleev Commun., 32:1 (2022), 35

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Mendeleev Communications, 2022, Volume 32, Issue 1, Pages 35–36
DOI: https://doi.org/10.1016/j.mencom.2022.01.010 (Mi mendc562)

This article is cited in 1 scientific paper (total in 1 paper)

Communications

Synthesis of Janus cube containing Si–H moieties

Ya. Egawa^ab, Ch. Kobuna^b, N. Takeda^b, M. Unno^b

^a Department of Chemistry, Faculty of Science, Kanagawa University, Kanagawa, Japan
^b Department of Chemistry and Chemical Biology, Graduate School of Science and Technology, Gunma University, Gunma, Japan

Full-text PDF (207 kB) Citations (1) Supplementary materials

DOI: https://doi.org/10.1016/j.mencom.2022.01.010

Graphic abstract: Synthesis of Janus cube containing Si–H moieties

Abstract: The first representative of the Janus cube with hydrogen substituents was obtained from all-cis-[BuⁱSiO(OH)]₄ by its capping with HSiCl₃ followed by gentle hydrolysis causing internal condensation. The compound has an extremely low maximum loss temperature, which is approximately halfway between H₈Si₈O₁₂ and (octaisobutyl)octasilsesquioxane.

Keywords: siloxanes, octasilsesquioxanes, organosilicon compounds, Janus particle, TG-DTA.

Bibliographic databases:

Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(709.1 Kb)

Citation: Ya. Egawa, Ch. Kobuna, N. Takeda, M. Unno, “Synthesis of Janus cube containing Si–H moieties”, Mendeleev Commun., 32:1 (2022), 35–36

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https://www.mathnet.ru/eng/mendc562

https://www.mathnet.ru/eng/mendc/v32/i1/p35

This publication is cited in the following 1 articles:

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