Abstract:
The reaction of phenyl-substituted dipotassium germacyclo-pentadienediide with one equivalent of hafnocene dichloride at low temperature provides a bicyclic germylene. With two equivalents of hafnocene dichloride, a dinuclear hafnium complex with a mmm-coordinating germolyl dianion ligand is formed.
Citation:
H. H. Cramer, L. Bührmann, M. Schmidtmann, T. Müller, “A phenyl-substituted germole dianion and its reaction with hafnocene dichloride”, Mendeleev Commun., 32:1 (2022), 46–48
Linking options:
https://www.mathnet.ru/eng/mendc566
https://www.mathnet.ru/eng/mendc/v32/i1/p46
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