T. Sasamori, T. Sugahara, N. Tokitoh, “Amidinate bromogermylene resulting from carbodiimide insertion into Ar–GeBr bond”, Mendeleev Commun., 32:1 (2022), 63

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Mendeleev Communications, 2022, Volume 32, Issue 1, Pages 63–65
DOI: https://doi.org/10.1016/j.mencom.2022.01.020 (Mi mendc572)

This article is cited in 1 scientific paper (total in 1 paper)

Communications

Amidinate bromogermylene resulting from carbodiimide insertion into Ar–GeBr bond

T. Sasamori^ab, T. Sugahara^c, N. Tokitoh^c

^a Department of Chemistry, University of Tsukuba, Tsukuba, Jupan
^b Graduate School of Science, Nagoya City University, Mizuho-cho, Mizuho-ku, Nagoya, Aichi, Japan
^c Institute for Chemical Research, Kyoto University, Gokasho, Uji, Kyoto, Japan

Full-text PDF (310 kB) Citations (1) Supplementary materials

DOI: https://doi.org/10.1016/j.mencom.2022.01.020

Graphic abstract: Amidinate bromogermylene resulting from carbodiimide insertion into Ar–GeBr bond

Abstract: The reaction of diaryldibromodigermene Tbb(Be)Ge = Ge(Br)Tbb (Tbb = 4-Bu^t-2,6-[CH(SiMe₃)₂]₂C₆H₂) with N,N'-diisopropyl-carbodiimide afforded the corresponding amidinato-supported bromogermylene via the insertion of the C=N moiety into the Ge–C(Tbb) sss-bond. The formation mechanism of the amidinato-supported bromogermylene was revealed by DFT calculations. This type of insertion reaction toward a metal–carbon bond can be interpreted in analogy to the reactivity of transition-metal complexes.

Keywords: Carbenoids, Germylenes, 1,2-Insertion, Main group elements, An amidinato ligand.

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Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(644.2 Kb)

Citation: T. Sasamori, T. Sugahara, N. Tokitoh, “Amidinate bromogermylene resulting from carbodiimide insertion into Ar–GeBr bond”, Mendeleev Commun., 32:1 (2022), 63–65

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This publication is cited in the following 1 articles:

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