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Mendeleev Communications, 2022, Volume 32, Issue 1, Pages 83–86
DOI: https://doi.org/10.1016/j.mencom.2022.01.027
(Mi mendc579)
 

This article is cited in 23 scientific papers (total in 23 papers)

Communications

Near-IR absorbing donor–acceptor charge-transfer gallium complex, an example from non-transition metal chemistry

A. V. Maleevaa, I. V. Ershovaa, O. Yu. Trofimovaa, K. V. Arsenyevaa, I. A. Yakushevb, A. V. Piskunova

a G.A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhnii Novgorod, Russian Federation
b N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
Abstract: Gallium(III) catecholates with bipyridine ligand [(3,5-Cat)Ga(bipy)2]I and (3,6-Cat)GaI(bipy) (Cat is di-tert-butylcatecholate) were synthesized and characterized by single-crystal X-ray diffraction. The appearance of near-infrared ligand-to-ligand charge transfer for pentacoordinate complex was observed.
Keywords: gallium, redox-active ligand, catecholate, diimine, X-ray diffraction, electronic spectroscopy.
Bibliographic databases:
Document Type: Article
Language: English
Supplementary materials:
Supplementary_data_1.pdf (917.1 Kb)


Citation: A. V. Maleeva, I. V. Ershova, O. Yu. Trofimova, K. V. Arsenyeva, I. A. Yakushev, A. V. Piskunov, “Near-IR absorbing donor–acceptor charge-transfer gallium complex, an example from non-transition metal chemistry”, Mendeleev Commun., 32:1 (2022), 83–86
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  • https://www.mathnet.ru/eng/mendc/v32/i1/p83
  • This publication is cited in the following 23 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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