M. V. Zelentsova, I. V. Sandulenko, E. K. Melnikova, S. K. Moiseev, “19F NMR determination of the C20 absolute configuration of C21-fluorinated arylthevinols”, Mendeleev Commun., 32:1 (2022), 97

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Mendeleev Communications, 2022, Volume 32, Issue 1, Pages 97–99
DOI: https://doi.org/10.1016/j.mencom.2022.01.031 (Mi mendc583)

This article is cited in 6 scientific papers (total in 6 papers)

Communications

¹⁹F NMR determination of the C²⁰ absolute configuration of C²¹-fluorinated arylthevinols

M. V. Zelentsova^a, I. V. Sandulenko^a, E. K. Melnikova^ab, S. K. Moiseev^a

^a A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
^b Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

Full-text PDF (392 kB) Citations (6) Supplementary materials

DOI: https://doi.org/10.1016/j.mencom.2022.01.031

Graphic abstract: <sup>19</sup>F NMR determination of the C<sup>20</sup> absolute configuration of C<sup>21</sup>-fluorinated arylthevinols

Abstract: 21,21,21-Trifluoro(aryl)thevinols were synthesized by the reaction of 21,21,21-trifluorothevinone with aryl Grignard reagents. The absolute configuration at C²⁰ atom in these CF₃-substituted alcohols can be easily determined by one-dimensional ¹⁹F NMR spectroscopy that was verified by X-ray diffraction studies.

Keywords: thevinone, thevinols, orvinols, alkaloids, organofluorine compounds, Grignard reaction, absolute configuration, ¹⁹F NMR.

Bibliographic databases:

Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(2.3 Mb)

Citation: M. V. Zelentsova, I. V. Sandulenko, E. K. Melnikova, S. K. Moiseev, “¹⁹F NMR determination of the C²⁰ absolute configuration of C²¹-fluorinated arylthevinols”, Mendeleev Commun., 32:1 (2022), 97–99

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https://www.mathnet.ru/eng/mendc/v32/i1/p97

This publication is cited in the following 6 articles:

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