K. E. Shepelenko, K. A. Nikolaeva, M. A. Shevchenko, Yu. N. Tkachenko, M. E. Minyaev, V. M. Chernyshev, “Ruthenium complexes with chelating carboxylate-NHC ligands as efficient catalysts for C–H arylation in water”, Mendeleev Commun., 32:2 (2022), 205

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Mendeleev Communications, 2022, Volume 32, Issue 2, Pages 205–207
DOI: https://doi.org/10.1016/j.mencom.2022.03.017 (Mi mendc614)

This article is cited in 11 scientific papers (total in 11 papers)

Communications

Ruthenium complexes with chelating carboxylate-NHC ligands as efficient catalysts for C–H arylation in water

K. E. Shepelenko^a, K. A. Nikolaeva^a, M. A. Shevchenko^a, Yu. N. Tkachenko^a, M. E. Minyaev^b, V. M. Chernyshev^a

^a Platov South-Russian State Polytechnic University, Novocherkassk, Russian Federation
^b N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Full-text PDF (506 kB) Citations (11) Supplementary materials

DOI: https://doi.org/10.1016/j.mencom.2022.03.017

Graphic abstract: Ruthenium complexes with chelating carboxylate-NHC ligands as efficient catalysts for C–H arylation in water

Abstract: Ruthenium(ii) complexes with chelating N-heterocyclic carbene (NHC) ligands were studied in the arylation of phenyl group in 2-phenylpyridine and 1-phenylpyrazole with aryl chlorides in water. Complexes with NHC-ligands containing a hemilabile coordinating N-carboxylatomethyl group enable fast and selective ortho-CH-diarylation in the absence of carboxylate-assisting additives.

Keywords: ruthenium complexes, CH-activation, arylation, N-heterocyclic carbene ligands, carboxylate assistance.

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Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(6.9 Mb)

Citation: K. E. Shepelenko, K. A. Nikolaeva, M. A. Shevchenko, Yu. N. Tkachenko, M. E. Minyaev, V. M. Chernyshev, “Ruthenium complexes with chelating carboxylate-NHC ligands as efficient catalysts for C–H arylation in water”, Mendeleev Commun., 32:2 (2022), 205–207

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https://www.mathnet.ru/eng/mendc/v32/i2/p205

This publication is cited in the following 11 articles:

Citing articles in Google Scholar: Russian citations, English citations
Related articles in Google Scholar: Russian articles, English articles

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