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Mendeleev Communications, 2022, Volume 32, Issue 2, Pages 208–211
DOI: https://doi.org/10.1016/j.mencom.2022.03.018 (Mi mendc615) 		 
This article is cited in 3 scientific papers (total in 3 papers)

Communications

Synthesis, crystal structure and thermal stability of new copper(II) trichloroacetate complexes

O. S. Pushikhina, K. R. Volkova, E. V. Karpova, V. A. Tafeenko, M. A. Zakharov

Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
Full-text PDF (1140 kB) Citations (3) Supplementary materials
DOI: https://doi.org/10.1016/j.mencom.2022.03.018
Abstract: We have synthesized two novel complexes of copper(II) trichloro acetate, Cu2(CCl3COO)3(OH)(H2O)4·H2O and Cu(CCl3COO)2(MeCN), and determined their crystal structures and thermal stability. While the complex with acetonitrile has a discrete binuclear paddle-wheel structure, typical of copper carboxylates, the aqua-hydroxo complex belongs to a novel unique chain–molecular type of basic copper complexes.
Keywords: basic copper salts, trichloroacetate, paddle wheel, acetonitrile solvate, crystal structure, thermal analysis.
Bibliographic databases:
Document Type: Article
Language: English
Supplementary materials:
Supplementary_data_1.pdf (932.4 Kb)


Citation: O. S. Pushikhina, K. R. Volkova, E. V. Karpova, V. A. Tafeenko, M. A. Zakharov, “Synthesis, crystal structure and thermal stability of new copper(II) trichloroacetate complexes”, Mendeleev Commun., 32:2 (2022), 208–211
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    • This publication is cited in the following 3 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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