Abstract:
A new protocol for Pd-catalyzed regioselective hydroxy-carbonylation of olefins with formic acid under low pressure of carbon monoxide has been developed. The same catalytic system provides good selectivity to 2-phenylpropionic acid in carbonylation of styrene and to linear acids in carbonylation of terminal alkenes. The reaction is highly susceptible to catalyst precursor and solvent nature.
Citation:
O. L. Eliseev, T. N. Bondarenko, M. V. Tsapkina, “An effective Pd-catalyzed hydroxycarbonylation of olefins with CO and HCOOH”, Mendeleev Commun., 32:2 (2022), 253–255
Linking options:
https://www.mathnet.ru/eng/mendc630
https://www.mathnet.ru/eng/mendc/v32/i2/p253
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