O. L. Eliseev, T. N. Bondarenko, M. V. Tsapkina, “Hydroxycarbonylation of vinyl acetate with formic acid: pathway to lactic acid and lactates”, Mendeleev Commun., 35:4 (2025), 472

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Mendeleev Communications, 2025, Volume 35, Issue 4, Pages 472–474
DOI: https://doi.org/10.71267/mencom.7657 (Mi mendc6335)

Communications

Hydroxycarbonylation of vinyl acetate with formic acid: pathway to lactic acid and lactates

O. L. Eliseev, T. N. Bondarenko, M. V. Tsapkina

N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation

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DOI: https://doi.org/10.71267/mencom.7657

Graphic abstract: Hydroxycarbonylation of vinyl acetate with formic acid: pathway to lactic acid and lactates

Abstract: The Pd-catalyzed hydroxycarbonylation of vinyl acetate in the presence of formic acid into 2-acetoxypropionic acid is reported. The reaction proceeds chemo- and regioselectively under very mild conditions of 80 °C and 3–6 bar CO.

Keywords: hydroxycarbonylation, palladium, carbon monoxide, formic acid, vinyl acetate, acetoxypropionic acid.

Received: 16.10.2024
Accepted: 27.12.2024

Published: 21.05.2025

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Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(196.7 Kb)

Citation: O. L. Eliseev, T. N. Bondarenko, M. V. Tsapkina, “Hydroxycarbonylation of vinyl acetate with formic acid: pathway to lactic acid and lactates”, Mendeleev Commun., 35:4 (2025), 472–474

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