Abstract:
Catalytic transfer hydrodechlorination of chlorobenzene using 2-propanol as the hydrogen donor and a mixed Ni–Mo sulfide phase deposited on alumina as the catalyst is studied at temperatures 250–300 °C. When triethylamine is applied as the HCl neutralizer, benzene is the only product, whereas with inorganic bases (iso)propylbenzenes are also formed.
Keywords:
transfer hydrodechlorination, nickel–molybdenum sulfide system, 2-propanol, chlorobenzene, benzene.
Citation:
A. S. Romanov, N. S. Nesterov, A. A. Salomatina, O. V. Klimov, V. P. Pakharukova, A. A. Philippov, I. V. Kozhevnikov, A. M. Chibiryaev, O. N. Martyanov, “Transfer hydrodechlorination of chlorobenzene over Ni–Mo sulfide system and effect of HCl neutralizer”, Mendeleev Commun., 35:3 (2025), 351–352
Linking options:
https://www.mathnet.ru/eng/mendc6429
https://www.mathnet.ru/eng/mendc/v35/i3/p351
This publication is cited in the following 1 articles: