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Mendeleev Communications, 2022, Volume 32, Issue 3, Pages 331–333
DOI: https://doi.org/10.1016/j.mencom.2022.05.012
(Mi mendc653)
 

This article is cited in 5 scientific papers (total in 5 papers)

Communications

Synthesis of unsymmetrical pincer CNN palladium complex of 8-dimethylamino-3-ferrocenylmethyl-3-azabicyclo[3.2.1]octane and its catalytic activity in the Suzuki reaction

L. A. Bulyginaa, N. S. Khrushchevaa, K. A. Lyssenkobc, A. S. Peregudova

a A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
b Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
c G.V. Plekhanov Russian University of Economics, Moscow, Russian Federation
Abstract: New bicyclic unsymmetrical CNN palladium 5,6-membered pincer complex was synthesized from 3-ferrocenylmethyl-8-dimethylamino-3-azabicyclo[3.2.1]octane by its direct cyclo-palladation with Li2PdCl4 or Na2PdCl4 and sodium acetate in MeOH. The obtained complex exhibited high catalytic activity in the Suzuki cross-coupling between aryl bromides and phenylboronic acid.
Keywords: unsymmetrical pincer complexes, palladium complexes, ferrocene, bicyclic ligand precursor, Suzuki reaction.
Bibliographic databases:
Document Type: Article
Language: English
Supplementary materials:
Supplementary_data_1.pdf (291.0 Kb)


Citation: L. A. Bulygina, N. S. Khrushcheva, K. A. Lyssenko, A. S. Peregudov, “Synthesis of unsymmetrical pincer CNN palladium complex of 8-dimethylamino-3-ferrocenylmethyl-3-azabicyclo[3.2.1]octane and its catalytic activity in the Suzuki reaction”, Mendeleev Commun., 32:3 (2022), 331–333
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  • This publication is cited in the following 5 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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