L. M. Kustov, A. N. Kalenchuk, V. I. Bogdan, “Dehydrogenation of N-ethyldodecahydrocarbazole over Pt/C catalyst in the hydrogen storage aspect”, Mendeleev Commun., 35:3 (2025), 356

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Mendeleev Communications, 2025, Volume 35, Issue 3, Pages 356–358
DOI: https://doi.org/10.71267/mencom.7652 (Mi mendc6584)

Communications

Dehydrogenation of N-ethyldodecahydrocarbazole over Pt/C catalyst in the hydrogen storage aspect

L. M. Kustov^abc, A. N. Kalenchuk^ab, V. I. Bogdan^ab

^a N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation
^b Department of Chemistry, M. V. Lomonosov Moscow State University, 119991 Moscow, Russian Federation
^c National University of Science and Technology MISiS, 119991 Moscow, Russian Federation

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DOI: https://doi.org/10.71267/mencom.7652

Graphic abstract: Dehydrogenation of <em>N</em>-ethyldodecahydrocarbazole over Pt/C catalyst in the hydrogen storage aspect

Abstract: The optimum conditions (T = 210 °C and V_L = 1 h^–1) were determined for the dehydrogenation of N-ethyldodecahydrocarbazole on a 3 wt% Pt/C catalyst in a flow-type catalytic unit at normal pressure. The kinetic parameters (conversion and selectivity) of the dehydrogenation process correlated well with the volumes of released hydrogen. High purity of the thus produced hydrogen was established by chromatography.

Keywords: hydrogen storage, hydrogenation, dehydrogenation, Pt/C catalyst, liquid organic hydrogen carriers, N-ethyldodecahydrocarbazole.

Funding agency	Grant number
Ministry of Science and Higher Education of the Russian Federation	project 075-15-2023-585

Received: 16.10.2024
Accepted: 09.12.2024

Published: 31.03.2025

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Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(266.6 Kb)

Citation: L. M. Kustov, A. N. Kalenchuk, V. I. Bogdan, “Dehydrogenation of N-ethyldodecahydrocarbazole over Pt/C catalyst in the hydrogen storage aspect”, Mendeleev Commun., 35:3 (2025), 356–358

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