A. E. Saifutiarova, Yu. V. Fedorov, E. E. Gulakova, O. A. Fedorova, “Mechanism of hydride abstraction in the electrocyclic phototransformation of heterostilbene”, Mendeleev Commun., 32:3 (2022), 374

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Mendeleev Communications, 2022, Volume 32, Issue 3, Pages 374–376
DOI: https://doi.org/10.1016/j.mencom.2022.05.027 (Mi mendc668)

This article is cited in 1 scientific paper (total in 1 paper)

Communications

Mechanism of hydride abstraction in the electrocyclic phototransformation of heterostilbene

A. E. Saifutiarova^ab, Yu. V. Fedorov^a, E. E. Gulakova^a, O. A. Fedorova^ab

^a A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
^b D.Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation

Full-text PDF (1135 kB) Citations (1) Supplementary materials

DOI: https://doi.org/10.1016/j.mencom.2022.05.027

Graphic abstract: Mechanism of hydride abstraction in the electrocyclic phototransformation of heterostilbene

Abstract: A new mechanism of hydride abstraction in the course of a photochemical electrocyclic reaction of heterostilbene in aqueous solution is reported. The study of electrocyclic transformations of heterostilbenes containing different types of heterocyclic residues revealed that the herein estimated mechanism of hydride abstraction is common for heterostilbene photochemical electrocyclization through the formation of new C–N bond.

Keywords: heterostilbenes, E–Z-photoisomerization, electrocyclization, hydride abstraction, regiospecific C–N photocyclization.

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Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(1.9 Mb)

Citation: A. E. Saifutiarova, Yu. V. Fedorov, E. E. Gulakova, O. A. Fedorova, “Mechanism of hydride abstraction in the electrocyclic phototransformation of heterostilbene”, Mendeleev Commun., 32:3 (2022), 374–376

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https://www.mathnet.ru/eng/mendc668

https://www.mathnet.ru/eng/mendc/v32/i3/p374

This publication is cited in the following 1 articles:

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