Abstract:
The reaction distyryl thioketone with donor alkenes (norbornene and styrene) gives adducts of the hetero-Diels–Alder reaction. In the case of maleic acid derivatives, a tandem reaction occurs which leads to polycyclic derivatives of 3,4-dihydro-2H-thiopyran. The stereochemical features of the ongoing transformations were examined.
Citation:
E. A. Merkulova, A. V. Kolobov, K. A. Lyssenko, V. G. Nenajdenko, “Diene-transmissive hetero-Diels–Alder reaction of distyryl thioketone”, Mendeleev Commun., 32:3 (2022), 384–385
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https://www.mathnet.ru/eng/mendc672
https://www.mathnet.ru/eng/mendc/v32/i3/p384
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