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Mendeleev Communications, 2022, Volume 32, Issue 4, Pages 485–487
DOI: https://doi.org/10.1016/j.mencom.2022.07.018
(Mi mendc702)
 

This article is cited in 8 scientific papers (total in 8 papers)

Communications

Ruthenium(II)-catalyzed C(3)–H arylation of furan moiety in fuberidazole derivatives

K. E. Shepelenkoa, K. A. Nikolaevaa, I. G. Gnatiuka, O. G. Garanzhaa, A. A. Alexandrova, M. E. Minyaevb, V. M. Chernysheva

a Platov South-Russian State Polytechnic University, Novocherkassk, Russian Federation
b N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
Abstract: An efficient selective C(3)–H arylation of furan ring in 2-(furan-2-yl)benzimidazoles, derivatives of fuberidazole fungicide, with aryl bromides catalyzed by [RuCl2(cymene)]2/ pivalic acid system has been accomplished. High selectivity of the process may be accounted for by the action of benzimidazol-2-yl substituent as the directing group.
Keywords: furans, CH-functionalization, arylation, ruthenium complexes, carboxylate assistance, 2-hetarylfurans, benzimidazoles.
Bibliographic databases:
Document Type: Article
Language: English
Supplementary materials:
Supplementary_data_1.pdf (5.3 Mb)


Citation: K. E. Shepelenko, K. A. Nikolaeva, I. G. Gnatiuk, O. G. Garanzha, A. A. Alexandrov, M. E. Minyaev, V. M. Chernyshev, “Ruthenium(II)-catalyzed C(3)–H arylation of furan moiety in fuberidazole derivatives”, Mendeleev Commun., 32:4 (2022), 485–487
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  • This publication is cited in the following 8 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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