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Mendeleev Communications, 2022, Volume 32, Issue 4, Pages 488–491
DOI: https://doi.org/10.1016/j.mencom.2022.07.019
(Mi mendc703)
 

This article is cited in 4 scientific papers (total in 4 papers)

Communications

Selective hydrogenation of α,β-unsaturated aldehydes over Pt supported on cerium–zirconium mixed oxide of different composition

K. V. Vikanovaa, E. A. Redinaa, G. I. Kapustina, I. V. Mishina, N. A. Davshana, L. M. Kustovabc

a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
b Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
c National University of Science and Technology 'MISIS', Moscow, Russian Federation
Abstract: Cerium–zirconium mixed oxides with different Ce/Zr ratio were prepared and used as supports for Pt-containing catalysts. The study of the catalysts in the cinnamaldehyde hydrogenation reaction has shown that cinnamaldehyde conversion and cinnamyl alcohol selectivity strongly depend on the CeO2 content in the support. The highest cinnamyl alcohol yield of 81% was obtained in 105 min at room temperature and atmospheric pressure over the 1%Pt/CeO2–ZrO2 catalyst with Ce : Zr atomic ratio equal to 4 : 1.
Keywords: cinnamaldehyde, cinnamyl alcohol, cerium oxide, zirconium oxide, selective hydrogenation, unsaturated alcohol synthesis, platinum, α,b-unsaturated aldehydes.
Bibliographic databases:
Document Type: Article
Language: English
Supplementary materials:
Supplementary_data_1.pdf (460.5 Kb)


Citation: K. V. Vikanova, E. A. Redina, G. I. Kapustin, I. V. Mishin, N. A. Davshan, L. M. Kustov, “Selective hydrogenation of α,β-unsaturated aldehydes over Pt supported on cerium–zirconium mixed oxide of different composition”, Mendeleev Commun., 32:4 (2022), 488–491
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  • This publication is cited in the following 4 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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