A. E. Tarakanova, M. A. Zherebtsov, M. V. Arsenyev, E. V. Baranov, S. A. Chesnokov, V. K. Cherkasov, “New tri-tert-alkyl substituted o-quinones of tetraline family”, Mendeleev Commun., 32:4 (2022), 540

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Mendeleev Communications, 2022, Volume 32, Issue 4, Pages 540–542
DOI: https://doi.org/10.1016/j.mencom.2022.07.035 (Mi mendc719)

This article is cited in 3 scientific papers (total in 3 papers)

Communications

New tri-tert-alkyl substituted o-quinones of tetraline family

A. E. Tarakanova^a, M. A. Zherebtsov^a, M. V. Arsenyev^ab, E. V. Baranov^a, S. A. Chesnokov^a, V. K. Cherkasov^ab

^a G.A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhnii Novgorod, Russian Federation
^b N.I. Lobachevsky State University of Nizhni Novgorod, Nizhni Novgorod, Russian Federation

Full-text PDF (429 kB) Citations (3) Supplementary materials

DOI: https://doi.org/10.1016/j.mencom.2022.07.035

Graphic abstract: New tri-<i>tert</i>-alkyl substituted <i>o</i>-quinones of tetraline family

Abstract: New tri-tert-alkyl substituted o-quinones of 3-tert-alkyl-5,5,8,8-tetramethyl-5,6,7,8-tetrahydronaphthalene-1,2-dione chemotype were obtained from phenol and 2,5-dichloro-2,5-dimethylhexane, with the SeO₂ oxidation of the sterically hindered phenol moiety having been performed at the final step. The electrochemical reduction of these quinones proceeds in two stages: the first reduction wave (E_1/2 = –0.60 ÷ –0.62 V) is reversible, while the second stage is irreversible.

Keywords: o-quinones, phenol, tetralines, alkylation, oxidation, selenium dioxide, X-ray study, electrochemistry.

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Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(575.2 Kb)

Citation: A. E. Tarakanova, M. A. Zherebtsov, M. V. Arsenyev, E. V. Baranov, S. A. Chesnokov, V. K. Cherkasov, “New tri-tert-alkyl substituted o-quinones of tetraline family”, Mendeleev Commun., 32:4 (2022), 540–542

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https://www.mathnet.ru/eng/mendc719

https://www.mathnet.ru/eng/mendc/v32/i4/p540

This publication is cited in the following 3 articles:

Citing articles in Google Scholar: Russian citations, English citations
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