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Mendeleev Communications, 2025, Volume 35, Issue 6, Pages 651–653
DOI: https://doi.org/10.71267/mencom.7862
(Mi mendc7339)
 

Communications

New phosphacoumarins containing aldehyde group: synthesis and properties

A. V. Zalaltdinovaa, N. O. Appazovb, Yu. M. Sadykovaa, A. S. Gazizova, N. I. Akylbekovb, K. Kh. Darmagambetb, R. A. Turmanovb, V. V. Syakaeva, D. P. Gerasimovaa, E. A. Chugunovaa, A. R. Burilova, O. G. Sinyashina

a A. E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, 420088 Kazan, Russian Federation
b Korkyt Ata Kyzylorda University, 120014 Kyzylorda, Kazakhstan
References:
Abstract: New phosphacoumarins containing an aldehyde group at the periphery were obtained in a ‘one-pot’ reaction of 2-ethoxyvinylphosphonic dichloride with 2,4-dihydroxybenzaldehyde derivatives. The further reaction of these compounds with 2,4-dinitrophenylhydrazine afforded new hydrazones which exist only as E-isomers.
Keywords: coumarins, phosphacoumarins, Friedel–Crafts reaction, cyclization, phosphorylation, hydrazones, organophosphorus compounds.
Funding agency Grant number
Russian Science Foundation 25-73-20015
Science Committee of the Ministry of Science and Higher Education of the Republic of Kazakhstan AP19677249
Received: 30.06.2025
Accepted: 07.08.2025
Published: 21.10.2025
Document Type: Article
Language: English
Supplementary materials:
Supplementary_data_1.pdf (2.3 Mb)


Citation: A. V. Zalaltdinova, N. O. Appazov, Yu. M. Sadykova, A. S. Gazizov, N. I. Akylbekov, K. Kh. Darmagambet, R. A. Turmanov, V. V. Syakaev, D. P. Gerasimova, E. A. Chugunova, A. R. Burilov, O. G. Sinyashin, “New phosphacoumarins containing aldehyde group: synthesis and properties”, Mendeleev Commun., 35:6 (2025), 651–653
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