V. E. Filatov, D. A. Iuzabchuk, B. N. Tarasevich, N. V. Zyk, E. K. Beloglazkina, “A convenient E-diastereoselective synthesis of NH-isatin N′-arylimines via the aza-Wittig reaction”, Mendeleev Commun., 32:5 (2022), 634

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Mendeleev Communications, 2022, Volume 32, Issue 5, Pages 634–636
DOI: https://doi.org/10.1016/j.mencom.2022.09.022 (Mi mendc750)

Communications

A convenient E-diastereoselective synthesis of NH-isatin N′-arylimines via the aza-Wittig reaction

V. E. Filatov, D. A. Iuzabchuk, B. N. Tarasevich, N. V. Zyk, E. K. Beloglazkina

Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

Full-text PDF (188 kB) Supplementary materials

DOI: https://doi.org/10.1016/j.mencom.2022.09.022

Graphic abstract: A convenient <i>E</i>-diastereoselective synthesis of <i>NH</i>-isatin <i>N′-</i>arylimines <i>via</i> the aza-Wittig reaction

Abstract: A general synthesis of NH-isatin N′-arylimines involves the aza-Wittig reaction of isatin and aryl azides, providing higher E-diastereoselectivity as compared to previously described methods. The procedure is applicable even to anilines which do not directly react with isatins.

Keywords: aryl isatin imines, aryl azides, imines, isatins, aza-Wittig reaction, stereoselectivity.

Bibliographic databases:

Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(4.5 Mb)

Citation: V. E. Filatov, D. A. Iuzabchuk, B. N. Tarasevich, N. V. Zyk, E. K. Beloglazkina, “A convenient E-diastereoselective synthesis of NH-isatin N′-arylimines via the aza-Wittig reaction”, Mendeleev Commun., 32:5 (2022), 634–636

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https://www.mathnet.ru/eng/mendc/v32/i5/p634

Citing articles in Google Scholar: Russian citations, English citations
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