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Mendeleev Communications, 2022, Volume 32, Issue 5, Pages 649–651
DOI: https://doi.org/10.1016/j.mencom.2022.09.027
(Mi mendc755)
 

This article is cited in 11 scientific papers (total in 11 papers)

Communications

1D CuI coordination polymers based on triphenylarsine and N,N'-ditopic co-ligands: synthesis, crystal structure and TADF properties

Ya. V. Demyanova, M. I. Rakhmanovaa, I. Yu. Bagryanskayab, A. V. Artem'eva

a A.V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
b N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
Abstract: 1D coordination polymers [Cu2I2(AsPh3)2(L)]n (L = 4,4'-bi-pyridine, pyrazine) were synthesized via the reaction of CuI with AsPh3 and N,N'-ditopic co-ligand s L. At ambient temperature, these polymers exhibit short-lived (2.3–3.2 μs) thermally activated delayed fluorescence (TADF) with max at 530 nm (L = 4,4'-bipyridine) and 605 nm (L = pyrazine) and quantum efficiency up to 45%.
Keywords: copper(I) iodide, triphenylarsine, coordination polymers, photoluminescence, thermally activated delayed fluorescence.
Bibliographic databases:
Document Type: Article
Language: English
Supplementary materials:
Supplementary_data_1.pdf (1.3 Mb)


Citation: Ya. V. Demyanov, M. I. Rakhmanova, I. Yu. Bagryanskaya, A. V. Artem'ev, “1D CuI coordination polymers based on triphenylarsine and N,N'-ditopic co-ligands: synthesis, crystal structure and TADF properties”, Mendeleev Commun., 32:5 (2022), 649–651
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  • This publication is cited in the following 11 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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